Let's Get Chemical
I tracked down these links while writing lecture notes for my chemistry class. I took three years of chemistry in college, and I worked in molecular genetics labs for ten or more years, but electron orbitals, redox, and radioactive isotope decay are things I've never had to explain to anyone else. That requires quite a bit of intense review, and chemistry was never a favorite topic of mine. The text for the course seemed a little thin on some topics, so I've gathered these links to fill in my memory gaps.
- General Chemistry Online from Fred Senese of the Chemistry Department of Frostburg State University. This is an attractive, fast-loading, very complete Web resource for chemistry students. This is the first place I'll be going for references.
- ThinkQuest Library index for Chemistry has Web pages on many chemistry topics, suitable for high school and early college students. The quality is high on the topics I've read through so far, and I was amazed to discover that these are written by students as part of a project sponsored by Oracle Education Foundation's ThinkQuest.
ThinkQuest inspires students to think, connect, create, and share. Students work in teams to build innovative and educational websites to share with the world. Along the way, they learn research, writing, teamwork, and technology skills and compete for exciting prizes. Sponsored by the Oracle Education Foundation, the competition offers a unique project-based learning experience to students and teachers across the globe. Everybody wins by having their completed websites published in the ThinkQuest Library, a rich online resource visited by millions monthly.
- ChemTutor is a text-based reference, with very good information. I wasn't able to find out who is responsible for it, and I found that curious. Still, it's a good resource. It describes itself thus:
Basic chemistry help is available here for high school or college students. Chemtutor begins with the fundamentals and gives expert help with the most difficult phases of understanding your first course in chemistry. Chemtutor is not necessarily a complete text for your course or a complete outline, but we are proud to offer some insightful help in the parts of primary chemistry that have been, from our experience, the hardest for students to grasp.
- The Biology Project from the Department of Biochemistry and Molecular Biophysics, University of Arizona. This site includes tutorials for someone needing to review basic chemistry for the biological sciences. They are well-done, and short enough to avoid discouraging the chemo-phobe.
- Curiosities Related to Chemistry from the Chemistry Teaching Resources, created by Knut Irgum and maintained by Svante Åberg at Umeå University, S-901 87 Umeå, Sweden. "This is an attempt to present a comprehensive list of chemistry teaching resources on the Internet." Sadly, quite a few of the links are dead, including the one I most wanted to revisit, that of some engineers at a Purdue University barbecue, lighting charcoal with liquid oxygen. Alas, it seems Perdue no longer wishes to display this early example of Internet viral video. (I first saw it about 11 years ago.) However, there are still links to alchemy, science jokes, and silly things students say to teachers. Lots of fun.
- Chemical Education Resource Shelf: Book reviews--chemistry texts, and other books of interest to chemists and science educators.
- Welcome to Wikibooks, a collection of free content textbooks that you can edit. The chemistry sections have some good content, but some topics just have stubs for now.
- George Cain's Online Mathematics Textbooks List:
The writing of textbooks and making them freely available on the web is an idea whose time has arrived. Most college mathematics textbooks attempt to be all things to all people and, as a result, are much too big and expensive. This perhaps made some sense when these books were rather expensive to produce and distribute--but this time has passed. A few years ago when I first posted a list of mathematics textbooks freely available on line, there existed only a handful of such books. Now there are many. The list here has grown and grown and is perhaps in serious need of some kind of organization into topics. There are also now many other sites at which there are links to on-line mathematics books and lecture notes.
- A Brief Review of Elementary Quantum Chemistry by C. David Sherrill of School of Chemistry and Biochemistry, Georgia Institute of Technology.
- ChemViz Curriculum Support Resources. This is a resource for students in a particular course, but I found it quite helpful.
- Physical Chemistry 351 at the University of Connecticut: Guided Readings.
- Organic Chemistry Help by a graduate student in Frostburg State University's chemistry department, who identifies himself only as chemhelper. (I'm guessing the stick figure portrait is male, but I could be wrong.)
- Virtual Textbook of Organic Chemistry by William Reusch. This is linked to Textbook Revolution, another group of free online texts and resources.
- Science & Engineering books for free download. More free texts online! .
J.J. Thomson's Experiments
When I was an undergraduate student, I believed my chemistry and physics professors hated me. I was a biological sciences major, and had to take large lecture sections with the 200-300 pre-med and pre-vet students. I know from personal experience that pre-med students are not much fun, so that probably explains the surly faculty. As a student, it was almost impossible for me to ask a question in lecture, and I never got a civil (let alone helpful) answer from a chemistry or physics professor in the three years I spent in those departments.
This was in sharp contrast to my experiences in all my other classes, from Chaucer to calculus to microbiology. Of course, I graduated loving Chaucer, and statistics, and botany....and hating chemistry. Of course, every science job I ever had after grad school was in biochemistry.
Now I'm teaching a college-level chemistry class, and having flashbacks to the seventies as I prepare lectures. I'm current on DNA, but haven't thought about electron shells, subshells, and orbitals much lately. That's how I got curious about John Thomson's nineteenth century experiments on subatomic particles and electromagnetic charges. My chemistry students were supposed to work through a little computer simulation on "how we discovered the mass of the electron," but we couldn't make it "come out right." When I did this in physics lab in 1976, with equipment old enough to have been original to Thomson's lab, we got the same non-result. I couldn't make sense of it then, but I was determined to figure it out this time. That's how I came to find these excellent links. There are some amazing student resources available now. I'm a bit jealous.
- Three Experiments, One Big Idea. This is an excellent explanation from the Center for the History of Physics. I'm slowly working my way through the many interesting chemistry and physics "exhibits" on their site.
- Joseph John Thomson (1856-1940): "Carriers of negative electricity." Nobel Lecture in Physics, December 11, 1906. [from Nobel Lectures: Physics, 1901-1921 (Amsterdam: Elsevier, 1967)]. The text of Thomson's Nobel Lecture. I was amazed to find I could follow it.
- J.J. Thompson's experiment and the charge-to-mass ratio of the electron. Mark E. Tuckerman of New York University has his lectures for General Chemistry I (Honors) available on line. The Thomson experiment lecture is quite clear and readable.
- A Brief History of the Electron from Egglescliffe's Physics Website.Their information is quite comprehensible, and this is their generous mission:
The idea behind the website is to encourage the study of physics at post-16 level and share ideas and educational material....Feel free to print/download these pages and use them in lessons / private study or starting points for www exploration. Any of the material in this website is freely available for anyone to use in their own educational web projects. If you want to acknowledge this site as a source fine, otherwise do not worry."
History of Carbohydrate Chemistry
In my continuing search for materials on the history of chemistry, I've been browsing the Web for carbohydrate chemistry. Here are some good sources. Reading about "how they came to know that" seems to help me understand and remember this material, which was always less than intuitive for me.
- Web Articles by Edwin Thall including several good history of chemistry topics. I found this set of articles via Stereochemistry, Thall's discussion of three-dimensional organic chemistry, and how "they figured it out."
- Chemical Heritage Foundation has extensive history of chemistry resources.
CHF maintains a world-class collection of materials that document the history and heritage of the chemical and molecular sciences, technologies, and industries; encourages research in CHF collections; and carries out a program of outreach and interpretation in order to advance an understanding of the role of the chemical and molecular sciences, technologies, and industries in shaping society.
Poetry, Newton, and Alchemy
Here are some excerpts from an interview on Newton's alchemy with historian Bill Newman, who has some interesting things to say about alchemy, poetry, and riddles. It's no wonder alchemy interested both John Donne and Isaac Newton.
[A]lchemy has been portrayed as the epitome of irrationality and a sort of avaricious folly....But we now know that most of the great minds of the [seventeenth and eighteenth centuries] were involved in alchemy, including Robert Boyle, John Locke, Leibniz, any number of others....[Alchemy] became legal during Newton's time. But why was it illegal? There's a long association, for good reasons, between alchemy and counterfeiting.
....[Newton] thought that alchemy promised tremendous control over the natural world. It would allow you to transmute virtually anything into anything else, not just lead into gold. There are other things, too, that probably were in Newton's mind. For example, alchemists realized that if the philosophers' stone were real and it got out to the public, it would ruin the gold standard.
....[T]his was the enigmatic language of alchemy. I mean "enigmatic" in a quite strict sense: it was a riddling language. The best way to look at these metaphors is in the light of riddles....the "menstrual blood of the sordid whore" is decipherable. It means simply the metalline form of antimony. That is the "menstrual blood" that's extracted from the "sordid whore," which is the ore of antimony.
It is a code, and it's clear that the alchemists delighted in this code. It's almost a form of poetry. In fact, lots of alchemists wrote in the form of poetry, quite literally.
....Newton was reading alchemists over a period of time, ranging over perhaps a thousand years, and there was a lot of development in these treatises. But Newton generally thinks they're all saying the same thing, so that's a problem....he was weaving together extracts from different authors, trying to make sense out of them. I think alchemy was the ultimate riddle. Newton delighted in riddles, and this provided a challenge to him that he just couldn't resist.
My inevitable list of links:
- The Alchemy Website. A broad range of articles, illustrations, and essays on the many meanings of alchemy.
- An interview on Newton's alchemy with historian Bill Newman. Part of Newton's Dark Secrets PBS (November 15, 2005)
-
Isaac Newton by James Gleick (2003) is an excellent biography of Sir Isaac Newton. I had previously read quite a bit about Newton, but I couldn't seem to form a mental image of the man or his environment. Gleick interweaves the scant Newtonian biographical material with the political, economic, and science history.
- James Gleick has a very interesting internet site, around.com, where he archives some essays, reviews, and an ecclectic collection of links. It hasn't been updated recently, but there's plenty here to amuse and instruct.
Chemistry Lessons and John Donne
I'm preparing another chemistry lecture, and I keep coming back to John Donne. It may seem strange, but it's all connected in my head. I suspected the Bridgid in Cyberspace celebrants might find the final couplet of Donne poem Love's Alchemy a little, well, misogynistic, so I went with a The Relic (equally strange and blasphemous in its own way). But my reading lately has included some history of chemistry, including its early roots in alchemy. Here's Donne's chemistry connection:
Some that have deeper digg'd love's mine than I,
Say, where his centric happiness doth lie.
I have loved, and got, and told,
But should I love, get, tell, till I were old,
I should not find that hidden mystery.
O! 'tis imposture all ;
And as no chemic yet th' elixir got,
But glorifies his pregnant pot,
If by the way to him befall
Some odoriferous thing, or medicinal,
So, lovers dream a rich and long delight,
But get a winter-seeming summer's night.
Our ease, our thrift, our honour, and our day,
Shall we for this vain bubble's shadow pay?
Ends love in this, that my man
Can be as happy as I can, if he can
Endure the short scorn of a bridegroom's play?
That loving wretch that swears,
'Tis not the bodies marry, but the minds,
Which he in her angelic finds,
Would swear as justly, that he hears,
In that day's rude hoarse minstrelsy, the spheres.
Hope not for mind in women ; at their best,
Sweetness and wit they are, but mummy, possess'd.
Here's my usual list of links:
- The Alchemy Website. A broad range of articles, illustrations, and essays on the many meanings of alchemy.
- An interview on Newton's alchemy with historian Bill Newman. Part of Newton's Dark Secrets PBS Airdate: November 15, 2005
- General, Organic and Biochemistry, courtesy of James K. Hardy and the University of Akron. An excellent quick reference to the chemistry I'm concerned with now.